It is the International Scientific Review of the Ethical Packaging Charter Foundation. A bimonthly publication in which 7 multidisciplinary articles are presented, relating to packaging, selected by several magazines of the digital science world.
In this Number:
Sustainable Management of Microplastic Pollutions from PET Bottles: Overview and Mitigation Strategies
The widespread use of polyethylene terephthalate (PET) in bottled water packaging remains significant and is expected to increase further in the coming years. This trend raises concerns due to the generation of large amounts of waste. The degradation of PET leads to the release of low-molecular-weight substances and microplastic particles, which contaminate food products and the environment. This work highlights the significance of microplastic pollution, summarizes the mechanisms of PET degradation, and discusses methods for microplastic detection. A key section of the paper explores potential degradation management strategies, focusing on their applications and existing limitations. The study underscores the need for coordinated action among the scientific community, industry, and policymakers to mitigate this pressing environmental challenge.
https://www.mdpi.com/2076-3417/15/10/5322
A Systematic Review of Driving Sustainability Through Circular Economy Marketing: Insights and Strategies for Green Marketing Innovation
Circular economy marketing (CEM) represents an innovative approach to aligning business strategies with sustainability objectives. This paper explores the role of CEM as a driver of green marketing innovation, emphasising strategies that minimise environmental impact on business competitiveness while enhancing consumer engagement. Using a systematic literature review based on the PRISMA methodology, we identified 39 high-impact studies across multiple industries, categorising findings into key themes, theoretical frameworks, and marketing strategies. The analysis highlights emerging trends, including the shift toward product-service systems (PSSs), behavioural nudging, transparent sustainability branding, and integration of digital technologies such as AI and blockchain to enhance traceability and consumer trust. Findings reveal that while circular economy marketing presents opportunities for businesses to differentiate themselves and build long-term sustainability strategies, significant challenges remain, including scalability issues, consumer scepticism, and risks of greenwashing. Moreover, gaps in standardising impact measurement and industry-specific adaptation hinder wider implementation. Business model innovation, policy support, and collaborative efforts are crucial in overcoming these barriers. This study provides insights for businesses, policymakers, and researchers, highlighting how CEM fosters green innovation and competitiveness. Future research should compare the effectiveness of various strategies to accelerate the transition toward sustainable marketing practices through regulation and interdisciplinary collaboration.
https://www.mdpi.com/2673-8392/5/2/61
Silk-Soy Alloy Materials: Influence of Silk Types (Mori, Thai, Muga, Tussah, and Eri) on the Structure, Properties, and Functionality of Insect–Plant Protein Blends (II)
Natural proteins present a sustainable and biocompatible alternative to conventional fossil fuel-derived plastics, with versatile applications in fields ranging from medicine to food packaging. Extending our previous research on silk–corn zein composites, this study utilizes soy protein—another plant protein extensively employed within biomedical applications—in conjunction with silk fibroin proteins extracted from a variety of domestic (Mori and Thai) and wild (Muga, Tussah, and Eri) silkworm species. By combining these proteins in varying ratios (0%, 10%, 25%, 50%, 75%, 90%, and 100%), silk–soy films were successfully fabricated with high miscibility. The structural and thermal stability of these films was confirmed through various characterization techniques, including Fourier transform infrared spectroscopy (FTIR), differential scanning calorimetry (DSC), and scanning electron microscopy (SEM). Structural refinements were then achieved through post-water annealing treatments. After annealing, it was observed that when soy protein was introduced into both types of silk, the silks exhibited a greater amount of intermolecular and intramolecular β-sheet content. This phenomenon can be attributed to soy’s intrinsic ability to self-assemble into β-sheets through electrostatic and hydrophobic interactions, which also improved the overall thermal stability and morphology of the composite films. The unique self-assembling properties of soy and its ability to promote β-sheet formation facilitate the customization of the silk source and the soy-to-silk ratio. This adaptability establishes protein-based thin films as a versatile and sustainable option for diverse applications in fields such as medicine, tissue engineering, food packaging, and beyond.
https://www.mdpi.com/1422-0067/26/10/4563
Evaluating the Chemical Resistance and Performance of Thermochromic Polymers for Food Packaging
The use of thermochromic pigments in food packaging offers several advantages, including improved food safety, waste reduction, and temperature change monitoring. However, little is known about how chemically resilient these materials are, especially regarding optical stability, thermochromic activation, and mechanical integrity following exposure to acidic, alkaline, oil-based, and neutral food-contact environments. This study evaluates the chemical resistance, thermal cycling effects, and mechanical durability of thermochromic pigment–polymer blends. Thermochromic polymer samples were subjected to multiple chemical environments, repeated thermal cycling, and mechanical analysis to assess degradation behavior. The findings show that virgin food-grade polymer with no thermochromic pigment sustains its performance stability throughout chemical exposure with little degradation. However, thermochromic polymer blends experienced reduced thermochromic functionality. This study offers insight into how well thermochromic pigment can be incorporated into intelligent food packaging despite the limitations associated with chemical exposure.
https://www.mdpi.com/1996-1944/18/9/2085
High-Resolution Mass Spectrometry for Identification, Quantification, and Risk Assessment of 40 PFAS Migrating from Microwave Popcorn Bags
Perfluoroalkyl and polyfluoroalkyl substances (PFASs) are widely utilized in food contact materials (FCMs) due to their water- and oil-repellent properties, yet their potential migration into food raises significant health concerns. This study employs high-resolution mass spectrometry (HRMS) to quantify the migration of 40 PFAS from microwave popcorn bags and assess the associated health risks. HRMS offers high mass accuracy and resolution, enabling precise detection of a broad spectrum of PFASs, including those with low migration levels. Migration experiments were conducted using 10% ethanol and 50% ethanol as food simulants at 70 °C for 2 h. The results indicate that when risk assessment is based solely on the European Food Safety Authority’s (EFSA) tolerable weekly intake (TWI) for four PFAS, hazard ratio (HR) values range from 0.01 to 0.8, suggesting minimal risk. However, when all PFAS are converted into perfluorooctanoic acid equivalents (PEQs) and compared against the U.S. Environmental Protection Agency’s (EPA’s) reference dose (RfD), HR values range from 0.3 to 142.3, indicating a significantly elevated health risk. These findings emphasize the necessity of comprehensive risk assessments incorporating the cumulative effects of all PFAS to better understand potential human exposure and inform regulatory policies.
https://www.mdpi.com/1420-3049/30/9/1989
Fully Biobased Composite from Lignocellulosic Plantain Waste with Potential Use in the Manufacture of Lollipop Sticks
Lollipop sticks were developed with fully biobased materials made of different plantain by-products, using extrusion processing followed by hot compression molding. The thermoplastic matrix was constituted of flour and starch from plantain bunch pulp and plantain peel cake. At the same time, two types of reinforcement were used, one of them being yarn from the lignocellulosic fibers of the pseudostem sheaths to constitute the BC1 lollipop stick and the other directly from the plantain pseudostem treated sheath to establish the BC2 lollipop stick. The biobased lollipop sticks were characterized in the migration test, finding a higher structural stability in lipophilic foods, with chocolate chosen as a confection to undergo physicochemical, structural, mechanical, and dynamic–mechanical characterization when interacting with the two biobased lollipop sticks until post-consumption was reached. The BC2 lollipop stick was characterized by maintaining higher stability in maximum tensile strength (12.62 to 11.76 MPa), higher flexural strength (19.07 to 10.11 MPa), storage modulus (4.97 to 1.65 GPa at 30 °C), and Tan delta (66.90 to 52.64 °C).
https://www.mdpi.com/2673-4176/6/2/41
Rethinking PE-HD Bottle Recycling—Impacts of Reducing Design Variety
As the severe environmental impacts of plastic pollution demand determined action, the European Union (EU) has included recycling at the core of its policies. Consequently, evolving jurisdiction now aims to achieve a recycling rate of 65% for non-PET plastic bottles by 2040. However, the widespread use of post-consumer high-density polyethylene (rPE-HD) recyclates in household chemical containers is still limited by PP contamination, poor mechanical properties, and low environmental stress cracking resistance (ESCR). Although previous studies have explored the improvement of regranulate properties through additives, few have examined whether reducing the variety of extrusion blow-moulded PE-HD packaging could offer similar benefits. Therefore, two sorted fractions of rPE-HD hollow bodies were processed into regranulates under industrial conditions, including hot washing, extrusion, and deodorisation. Subsequently, both materials underwent comprehensive characterisation regarding their composition and performance. The opaque material, which was sourced from milk bottles in the UK, exhibited greater homogeneity with minor impurities, leading to improved ductility and melt strain hardening at moderate strain rates compared to the mixed material stream, which contained approximately 2.5% PP contamination. However, both rPE-HD recyclates exhibited similar short-term creep behaviour, relatively low strain hardening moduli, and were almost devoid of inorganic particles. Considering the sum of the investigated properties, melt blending with suitable virgin material is likely one of the most effective options to maximise regranulate utilisation in hollow bodies, followed by recycling-oriented packaging design (e.g., for efficient sorting), and the employment of advanced sorting technology.
https://www.mdpi.com/2313-4321/10/3/93
